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Categories: Chemistry: General, Environmental: Ecosystems
Published Growing triple-decker hybrid crystals for lasers
(via sciencedaily.com) By controlling the arrangement of multiple inorganic and organic layers within crystals using a novel technique, researchers have shown they can control the energy levels of electrons and holes (positive charge carriers) within a class of materials called perovskites. This tuning influences the materials' optoelectronic properties and their ability to emit light of specific energies, demonstrated by their ability to function as a source of lasers.
Published Arctic soil methane consumption may be larger than previously thought and increases in a drier climate
(via sciencedaily.com) Original source A recent study finds that Arctic soil methane uptake may be larger than previously thought, and that methane uptake increases under dry conditions and with availability of labile carbon substrates.
Published Coastal fisheries show surprising resilience to marine heat waves
(via sciencedaily.com) New research found that marine heat waves -- prolonged periods of unusually warm ocean temperatures -- haven't had a lasting effect on the fish communities that feed most of the world. The finding is in stark contrast to the devastating effects seen on other marine ecosystems cataloged by scientists after similar periods of warming, including widespread coral bleaching and harmful algal blooms.
Published Taking photoclick chemistry to the next level
(via sciencedaily.com) Researchers have been able to substantially improve photoclick chemistry. They were able to boost the reactivity of the photoclick compound in the popular PQ-ERA reaction through strategic molecular substitution. They now report a superb photoreaction quantum yield, high reaction rates and notable oxygen tolerance.
Published Using evidence from last Ice Age, scientists predict effects of rising seas on coastal habitats
(via sciencedaily.com) Original source The rapid sea level rise and resulting retreat of coastal habitat seen at the end of the last Ice Age could repeat itself if global average temperatures rise beyond certain levels, according to an analysis by an international team of scientists.
Published Emphasizing the need for energy independence could change the views of climate deniers, study says
(via sciencedaily.com) Original source Emphasising the need for energy independence and environmental stewardship could help to change people’s minds about the climate crisis, a new study says.
Published Can this forest survive? Predicting forest death or recovery after drought
(via sciencedaily.com) Original source New work could help forest managers predict which forests are most at risk from drought and which will survive.
Published Surpassing the human eye: Machine learning image analysis rapidly determines chemical mixture composition
(via sciencedaily.com) Machine learning model provides quick method for determining the composition of solid chemical mixtures using only photographs of the sample.
Published Direct formation of sulfuric acid in the atmosphere
(via sciencedaily.com) In the atmosphere, gaseous sulfuric acid can form particles that influence the physical properties of clouds. Thus, the formation of sulfuric acid in the gas phase directly affects the radiative forcing and Earth's climate. In addition to the known formation from sulfur dioxide, researchers have now been able to demonstrate through experiments that there is another formation pathway that has been speculated about for decades. Sulfuric acid in the atmosphere can also be formed directly by the oxidation of organic sulfur compounds. This new production pathway can be responsible for up to half of the gaseous sulfuric acid formation over the oceans and is thus of high importance for climate projections -- especially over the oceans of the Southern Hemisphere.
Published New 'droplet battery' could pave the way for miniature bio-integrated devices
(via sciencedaily.com) Researchers have developed a miniature battery that could be used to power tiny devices integrated into human tissues. The design uses an ionic gradient across a chain of droplets -- inspired by how electric eels generate electricity. The device was able to regulate the biological activity of human neurons. This could open the way to the development of tiny bio-integrated devices, with a range of applications in biology and medicine.
Published After Chernobyl nuclear accident: The wild boar paradox, finally solved
(via sciencedaily.com) Original source While the contamination of deer and roe deer decreased over time as expected, the measured levels of radioactivity in the meat of wild boar remained surprisingly high -- higher than the half-life of cesium would suggest. For many years, this 'wild boar paradox' was considered unsolved. Now an explanation has been found: It is a late aftermath of the nuclear weapons tests from the 1960s.
Published Want to fight climate change? Don't poach gorillas (or elephants, hornbills, toucans, etc.)
(via sciencedaily.com) Original source A new article found that overhunting of gorillas, elephants, and other large fruit-eating seed-dispersers make tropical forests less able to store or sequester carbon.
Published Overcoming the challenges to synthesising iron--sulfur proteins outside the glovebox
(via sciencedaily.com) Iron--sulfur (Fe--S) proteins, essential to all life forms, are difficult to synthesise due to the complicated molecular machinery involved and sensitivity of Fe--S clusters to oxygen. In a new study, a team of researchers devised an innovative protocol for synthesising mature Fe--S proteins, by bringing together a recombinant sulfur assimilation (SUF) system and an oxygen-scavenging system, thereby, paving the way for new technologies and a better understanding of the evolution of life.
Published Wildfire, soil emissions increasing air pollution in remote forests
(via sciencedaily.com) Original source Nitrogen dioxide levels in remote forest areas are increasing, and wildfire and soil emissions are likely the reasons why, finds a new study.
Published A first for ferrocene: Organometallic capsule with unusual charge-transfer interactions
(via sciencedaily.com) An organometallic capsule that can reversibly assemble and disassemble in response to chemical stimuli was recently developed by chemists. Comprising ferrocene-based bent amphiphiles, this new capsule can act as a host for various types of guest molecules, such as electron acceptors and dyes. Thanks to the controllable release of its cargo, the capsule would find applications in catalysis, medicine, and biotechnology.
Published Direct power generation from methylcyclohexane using solid oxide fuel cells
(via sciencedaily.com) Original source Methylcyclohexane is very promising as a hydrogen carrier that can safely and efficiently transport and store hydrogen. However, the dehydrogenation process using catalysts has issues due to its durability and large energy loss. Recently, researchers have succeeded in using solid oxide fuel cells to generate electricity directly from methylcyclohexane and recover toluene for reuse. This research is expected to not only reduce energy requirements but also explore new chemical synthesis by fuel cells.
Published Enhanced chemical weathering: A solution to the climate crisis?
(via sciencedaily.com) Original source Could blending of crushed rock with arable soil lower global temperatures? Researchers study global warming events from 40 and 56 million years ago to find answers.
Published Broken by bison, aspen saplings having a tough time in northern Yellowstone
(via sciencedaily.com) In northern Yellowstone National Park, saplings of quaking aspen, an ecologically important tree in the American West, are being broken by a historically large bison herd, affecting the comeback of aspen from decades of over-browsing by elk.
Published Past abrupt changes in North Atlantic Overturning have impacted the climate system across the globe
(via sciencedaily.com) Original source Abrupt climate changes have affected rainfall patterns worldwide in the past, especially in the tropical monsoon region, a new study shows. An international team of scientists used dripstones from globally distributed caves together with model simulations to analyze the global impacts of rapid Northern-Hemisphere temperature increases, the widely studied Dansgaard-Oeschger events, that repeatedly occurred during the last ice age. The comparison of stalagmite and model data shows in unprecedented detail how these abrupt changes and the associated modifications of the Atlantic overturning circulation, AMOC for short, have affected global atmospheric circulation.
Published Due to sea-ice retreat, zooplankton could remain in the deep longer
(via sciencedaily.com) Original source Due to intensifying sea-ice melting in the Arctic, sunlight is now penetrating deeper and deeper into the ocean. Since marine zooplankton respond to the available light, this is also changing their behavior -- especially how the tiny organisms rise and fall within the water column. As an international team of researchers has now shown, in the future this could lead to more frequent food shortages for the zooplankton, and to negative effects for larger species including seals and whales.