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Categories: Chemistry: Organic Chemistry, Geoscience: Geochemistry

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Machine learning can be valuable in supporting sustainable development of biomass if it is applied across the entire lifecyle of biomass and biomass-derived products, according to a new study.

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The Phlegraean volcanic fields just west of Naples, Italy, are among the top eight emitters of volcanic carbon dioxide in the world. Since 2005, the Solfatara crater -- one of many circular depressions in the landscape left by a long history of eruptions --has been emitting increased volumes of gas. Today it emits 4,000-5,000 tons of carbon dioxide each day, equivalent to the emissions from burning ~500,000 gallons of gasoline. Researchers estimate that as much as 20%--40% of the current carbon dioxide emissions are from the dissolution of calcite in the rocks, while 60%--80% is from underground magma.

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Milutin Milankovitch hypothesized that the timing of glacial transitions has been controlled by the orbital parameters of the Earth, which suggests that there may be some predictability in the climate, a notoriously complex system. Now researchers propose a new paradigm to simplify the verification of the Milankovitch hypothesis. The new 'deterministic excitation paradigm' combines the physics concepts of relaxation oscillation and excitability to link Earth's orbital parameters and the glacial cycles in a more generic way.

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Researchers have developed a dual-purpose catalyst that purifies herbicide-tainted water while also producing hydrogen.

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A team of researchers has made a discovery that may have implications for therapeutic gene editing strategies, cancer diagnostics and therapies and other advancements in biotechnology.

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Quantum effects can play an important role in chemical reactions. Physicists have now observed a quantum mechanical tunneling reaction in experiments. The observation can also be described exactly in theory. The scientists provide an important reference for this fundamental effect in chemistry. It is the slowest reaction with charged particles ever observed.

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Certain diseases, including Alzheimer's, are currently considered 'undruggable' because traditional small molecule drugs can't interfere with the proteins responsible for the illnesses. But a new technique that specifically targets and breaks apart certain proteins -- rather than just interfering with them -- may offer a pathway toward treatment. Researchers have now designed a compound that targets and breaks down a post-translationally modified protein closely associated with Alzheimer's disease.

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Engineers devised a way to purify protein drugs during manufacturing. Their approach, which uses nanoparticles to rapidly crystallize proteins, could help make protein drugs more affordable and accessible, especially in developing countries.

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A new hybrid hydrogel that safely delivers stem cells to brain injury sites in mice has been developed. This solves a major challenge -- keeping stem cells alive for long enough to evolve into the cells required to create new tissue after insertion into a damaged part of the body.

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Researchers have succeeded in producing very special catalysts, known as 'Lewis superacids', which can be used to break strong chemical bonds and speed up reactions. The production of these substances has, until now, proven extremely difficult. The chemists' discovery enables non-biodegradable fluorinated hydrocarbons, similar to Teflon, and possibly even climate-damaging greenhouse gases, such as sulphur hexafluoride, to be converted back into sustainable chemicals.

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Chaotic behavior is typically known from large systems: for example, from weather, from asteroids in space that are simultaneously attracted by several large celestial bodies, or from swinging pendulums that are coupled together. On the atomic scale, however, one does normally not encounter chaos -- other effects predominate. Now scientists have been able to detect clear indications of chaos on the nanometer scale -- in chemical reactions on tiny rhodium crystals.

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A series of new stable, porous materials that capture and separate benzene have been developed.

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A team has developed a method for selectively manipulating genetically engineered cells with ultrasound.

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The boundaries between biology and technology are becoming blurred. Researchers have now successfully grown electrodes in living tissue using the body's molecules as triggers. The result paves the way for the formation of fully integrated electronic circuits in living organisms.

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An air filter made out of corn protein instead of petroleum products can concurrently capture small particulates as well as toxic chemicals like formaldehyde that current air filters can't. The research could lead to better air purifiers, particularly in regions of the world that suffer from very poor air quality. The more environmentally friendly air filter was able to simultaneously capture 99.5% of small particulate matter, similar to commercial HEPA filters, and 87% of formaldehyde, which is higher than specially designed air filters for those types of toxics.

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Theoretical chemists have developed a theory that can predict the threshold at which quantum dynamics switches from 'orderly' to 'random,' as shown through research using large-scale computations on photosynthesis models.

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Researchers create a network of interacting proteins -- or interactome -- to aid drug discovery.

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RNAs can wreak havoc on cells if they aren't removed at the right time. Dis3L2 is a molecular 'machine' that untangles and chews up RNAs, but scientists have been unable to explain how. Biochemists have now pieced together the answer. By shape-shifting, the machine unsheathes a lethal wedge that pries open and chews up RNA molecules, a behavior previously unseen.

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Scientists recently announced the invention of a nanowire 10,000 times thinner than a human hair that can be cheaply grown by common bacteria and tuned to 'smell' a vast array of chemical tracers -- including those given off by people afflicted with a wide range of medical conditions, such as asthma and kidney disease. Thousands of these specially tuned wires, each sniffing out a different chemical, can be layered onto tiny, wearable sensors, allowing healthcare providers an unprecedented tool for monitoring potential health complications. Since these wires are grown by bacteria, they are organic, biodegradable and far greener than any inorganic nanowire.

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Scientists have used machine learning to create brand-new enzymes, which are proteins that accelerate chemical reactions. This is an important step in the field of protein design as new enzymes could have many uses across medicine and industrial manufacturing. The research team devised deep-learning, artificial intelligence algorithms that created light-emitting enzymes called luciferases. Laboratory testing confirmed that the new enzymes can recognize specific chemicals and emit light very efficiently.