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Categories: Chemistry: Inorganic Chemistry
Published Catalyst for electronically controlled C--H functionalization
(via sciencedaily.com) Original source Scientists chipping away at one of the great challenges of metal-catalyzed C--H functionalization with a new method that uses a cobalt catalyst to differentiate between bonds in fluoroarenes, functionalizing them based on their intrinsic electronic properties. And their method is fast -- comparable in speed to those that rely on iridium.
Published Bowtie resonators that build themselves bridge the gap between nanoscopic and macroscopic
(via sciencedaily.com) Original source Two nanotechnology approaches converge by employing a new generation of fabrication technology. It combines the scalability of semiconductor technology with the atomic dimensions enabled by self-assembly.
Published Chemists create organic molecules in a rainbow of colors
(via sciencedaily.com) Original source Chemists have now come up with a way to make molecules known as acenes more stable, allowing them to synthesize acenes of varying lengths. Using their new approach, they were able to build molecules that emit red, orange, yellow, green, or blue light, which could make acenes easier to deploy in a variety of applications.
Published Researchers decode aqueous amino acid's potential for direct air capture of CO2
(via sciencedaily.com) Original source Scientists have made a significant stride toward understanding a viable process for direct air capture, or DAC, of carbon dioxide from the atmosphere. This DAC process is in early development with the aim of achieving negative emissions, where the amount of carbon dioxide removed from the envelope of gases surrounding Earth exceeds the amount emitted.
Published Harvesting more solar energy with supercrystals
(via sciencedaily.com) Original source Hydrogen is a building block for the energy transition. To obtain it with the help of solar energy, researchers have developed new high-performance nanostructures. The material holds a world record for green hydrogen production with sunlight.
Published Control over friction, from small to large scales
(via sciencedaily.com) Original source Friction is hard to predict and control, especially since surfaces that come in contact are rarely perfectly flat. New experiments demonstrate that the amount of friction between two silicon surfaces, even at large scales, is determined by the forming and rupturing of microscopic chemical bonds between them. This makes it possible to control the amount of friction using surface chemistry techniques.
Published Researchers reveal new process for making anhydride chemical compounds
(via sciencedaily.com) Original source A collaborative research team has discovered a new process for making anhydrides that promises improvements in costs and sustainability.
Published Researchers show an old law still holds for quirky quantum materials
(via sciencedaily.com) Original source Long before researchers discovered the electron and its role in generating electrical current, they knew about electricity and were exploring its potential. One thing they learned early on was that metals were great conductors of both electricity and heat. And in 1853, two scientists showed that those two admirable properties of metals were somehow related: At any given temperature, the ratio of electronic conductivity to thermal conductivity was roughly the same in any metal they tested. This so-called Wiedemann-Franz law has held ever since -- except in quantum materials. Now, a theoretical argument put forth by physicists suggests that the law should, in fact, approximately hold for one type of quantum material, the cuprate superconductors.
Published Progress toward improved vaccines
(via sciencedaily.com) Original source To ensure that vaccines provide strong and lasting immunization, it is often necessary to supplement the actual vaccine (antigen) with additives that stimulate the immune system: adjuvants. Today, only a few substances have been approved for use as adjuvants. A research team has now introduced a spectrum of potential adjuvants. They started with the immune stimulant ?-glactosyl ceramide (?-GalCer) and synthesized many different variants from a set of four building blocks.
Published Durable plastic pollution easily, cleanly degrades with new catalyst
(via sciencedaily.com) Original source Found in fishing nets, carpet, clothing, Nylon-6 is a major contributor to plastic pollution, including ocean pollution. Now, chemists have developed a new catalyst that quickly, cleanly and completely breaks down Nylon-6 in a matter of minutes -- without generating harmful byproducts. Even better: The process does not require toxic solvents, expensive materials or extreme conditions, making it practical for everyday applications. In experiments, the new process recovered 99% of the polymer's building blocks, which can then be upcycled into higher-value products.
Published Artificial intelligence paves way for new medicines
(via sciencedaily.com) Original source Researchers have developed an AI model that can predict where a drug molecule can be chemically altered.
Published Greener solution powers new method for lithium-ion battery recycling
(via sciencedaily.com) Original source Used lithium-ion batteries from cell phones, laptops and a growing number of electric vehicles are piling up, but options for recycling them remain limited mostly to burning or chemically dissolving shredded batteries. Researchers have improved on approaches that dissolve the battery in a liquid solution in order to reduce the amount of hazardous chemicals used in the process. This simple, efficient and environmentally-friendly solution overcomes the main obstacles presented by previous approaches.
Published Compact accelerator technology achieves major energy milestone
(via sciencedaily.com) Original source Researchers have demonstrated a compact particle accelerator less than 20 meters long that produces an electron beam with an energy of 10 billion electron volts (10 GeV). There are only two other accelerators currently operating in the U.S. that can reach such high electron energies, but both are approximately 3 kilometers long. This type of accelerator is called a wakefield laser accelerator.
Published Chemists use oxygen, copper 'scissors' to make cheaper drug treatments possible
(via sciencedaily.com) Original source Researchers have devised a way to produce chemicals used in medicine and agriculture for a fraction of the usual cost. Using oxygen as a reagent and copper as a catalyst to break organic molecules' carbon-carbon bonds and convert them into amines, which are widely used in pharmaceuticals. Traditional metal catalysis uses expensive metals such as platinum, silver, gold and palladium, but the researchers used oxygen and copper -- an abundant base metal.
Published Hybrid transistors set stage for integration of biology and microelectronics
(via sciencedaily.com) Original source Researchers create transistors combining silicon with biological silk, using common microprocessor manufacturing methods. The silk protein can be easily modified with other chemical and biological molecules to change its properties, leading to circuits that respond to biology and the environment.
Published Discovery of structural regularity hidden in silica glass
(via sciencedaily.com) Original source Glass is a fundamental material. Yet its atomic structure still baffles scientists to this day. Researchers have developed a new way to quantify ring shapes in chemically bonded networks of glass, chipping away at some of the mysteries behind glass's atomic structure.
Published Effect of aerosol particles on clouds and the climate captured better
(via sciencedaily.com) Original source Global measurements and model calculations show that the complex relationship between the chemistry and climate impact of aerosol particles can be successfully captured by a simple formula.
Published Putting an end to plastic separation anxiety
(via sciencedaily.com) Original source Bio-based plastics often end up in recycling streams because they look and feel like conventional plastic, but the contamination of these compostable products makes it much harder to generate functional material out of recycled plastic. Scientists have now developed a biology-driven process to convert these mixtures into a new biodegradable material that can be used to make fresh products. The scientists believe the process could also enable a new field of biomanufacturing wherein valuable chemicals and even medicines are made from microbes feeding off of plastic waste.
Published A deep-sea fish inspired researchers to develop supramolecular light-driven machinery
(via sciencedaily.com) Original source Chemists have developed a bioinspired supramolecular approach to convert photo-switchable molecules from their stable state into metastable one with low-energy red light. Their work enables fast, highly selective, and efficient switching, providing new tools for energy storage, activation of drugs with light, and sensing applications.
Published Novel measurement technique for fluid mixing phenomena using selective color imaging method
(via sciencedaily.com) Original source A novel measurement technique has been developed to visualize the fluid flow and distribution within two droplets levitated and coalesced in space using fluorescence-emitting particles. This technique enabled the estimation of fluid motion within each droplet, thereby revealing the internal flow caused by surface vibration when the droplet merging promotes fluid mixing.