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Categories: Chemistry: Inorganic Chemistry, Geoscience: Oceanography
Published First direct imaging of small noble gas clusters at room temperature
(via sciencedaily.com) Original source Scientists have succeeded in the stabilization and direct imaging of small clusters of noble gas atoms at room temperature. This achievement opens up exciting possibilities for fundamental research in condensed matter physics and applications in quantum information technology. The key to this breakthrough was the confinement of noble gas atoms between two layers of graphene.
Published Making an important industrial synthesis more environmentally friendly
(via sciencedaily.com) Original source Researchers have resolved a problem that has limited the environmental sustainability of peracid synthesis. By judicious choice of the solvent and light input, approximately room-temperature autoxidation of aldehydes proceeds in a manner that results in industrially useful peracids or carboxylic acids. This work is an important advance in green chemistry that will help minimize the carbon footprint of the chemical industry.
Published Researchers step closer to mimicking nature's mastery of chemistry
(via sciencedaily.com) Original source In nature, organic molecules are either left- or right-handed, but synthesizing molecules with a specific 'handedness' in a lab is hard to do. Make a drug or enzyme with the wrong 'handedness,' and it just won't work. Now chemists are getting closer to mimicking nature's chemical efficiency through computational modeling and physical experimentation.
Published Dry-cleaning fluid becomes a synthetic chemist's treasure
(via sciencedaily.com) Original source The widely used dry-cleaning and degreasing solvent perc can be converted to useful chemicals by a new clean, safe and inexpensive procedure. The discovery using on-demand UV activation may open the path to upcycling perc and thus contribute to a more sustainable society.
Published Focus on biological processes does not capture the whole picture
(via sciencedaily.com) Original source The ocean plays a crucial role in the storage of carbon dioxide (CO2). The so-called marine biological carbon pump is an important research topic in this context. However a key component is often overlooked. Colleagues outline why it is insufficient to focus solely on biological processes when investigating the accumulation of CO2 in the ocean by the biological carbon pump.
Published PFAS flow equally between Arctic Ocean and Atlantic Ocean
(via sciencedaily.com) Original source The frigid Arctic Ocean is far removed from the places most people live, but even so, 'forever chemicals' reach this remote landscape. Now, research suggests that per- and polyfluoroalkyl substances (PFAS) won't stay there indefinitely. Instead, they are transported in a feedback loop, with the Arctic Ocean potentially exporting as many PFAS to the North Atlantic Ocean as it receives, circulating the compounds around the world.
Published The reaction mechanism for catalytic ammonia production experimentally determined
(via sciencedaily.com) Original source Researchers have now been able to study the surface of iron and ruthenium catalysts when ammonia is formed from nitrogen and hydrogen. A better knowledge of the catalytic process and the possibility of finding even more efficient materials opens the door for a green transition in the currently very CO2-intensive chemical industry.
Published Epic of a molecular ion: With eyes of electrons
(via sciencedaily.com) Original source Researchers have achieved real-time capture of the ionization process and subsequent structural changes in gas-phase molecules through an enhanced mega-electronvolt ultrafast electron diffraction (MeV-UED) technique, enabling observation of faster and finer movements of ions.
Published Acidity of Antarctic waters could double by century's end, threatening biodiversity
(via sciencedaily.com) Original source Without drastically reducing global emissions, the Antarctic Ocean could become too acidic for hundreds of species living there, many already endangered by rising temperatures and sea ice loss.
Published How black silicon, a prized material used in solar cells, gets its dark, rough edge
(via sciencedaily.com) Original source Researchers have developed a new theoretical model explaining one way to make black silicon. The new etching model precisely explains how fluorine gas breaks certain bonds in the silicon more often than others, depending on the orientation of the bond at the surface. Black silicon is an important material used in solar cells, light sensors, antibacterial surfaces and many other applications.
Published The first domino falls for redox reactions
(via sciencedaily.com) Original source Transmitting an effect known as a domino reaction using redox chemistry has been achieved for the first time.
Published Researchers demonstrate that quantum entanglement and topology are inextricably linked
(via sciencedaily.com) Original source Researchers have demonstrated the remarkable ability to perturb pairs of spatially separated yet interconnected quantum entangled particles without altering their shared properties.
Published Chemists develop new approach to inserting single carbon atoms
(via sciencedaily.com) Original source Chemists have presented a new approach in which a single carbon atom is inserted into the carbon skeleton of cyclic compounds in order to adjust the ring size. The method could be relevant, for example, for the production of active ingredients in new pharmaceutical products.
Published Solid state battery design charges in minutes, lasts for thousands of cycles
(via sciencedaily.com) Original source Researchers have developed a new lithium metal battery that can be charged and discharged at least 6,000 times -- more than any other pouch battery cell -- and can be recharged in a matter of minutes. The research not only describes a new way to make solid state batteries with a lithium metal anode but also offers new understanding into the materials used for these potentially revolutionary batteries.
Published Bottled water can contain hundreds of thousands of previously uncounted tiny plastic bits
(via sciencedaily.com) Original source In recent years, there has been rising concern that tiny particles known as microplastics are showing up basically everywhere on Earth, from polar ice to soil, drinking water and food. Formed when plastics break down into progressively smaller bits, these particles are being consumed by humans and other creatures, with unknown potential health and ecosystem effects. One big focus of research: bottled water, which has been shown to contain tens of thousands of identifiable fragments in each container. Now, using newly refined technology, researchers have entered a whole new plastic world: the poorly known realm of nanoplastics, the spawn of microplastics that have broken down even further. For the first time, they counted and identified these minute particles in bottled water. They found that on average, a liter contained some 240,000 detectable plastic fragments -- 10 to 100 times greater than previous estimates, which were based mainly on larger sizes.
Published Arctic cold snap transforms into a blessing
(via sciencedaily.com) Original source Scientists investigate the influence of Arctic cold air on carbon dioxide uptake of the east sea.
Published Using berry phase monopole engineering for high-temperature spintronic devices
(via sciencedaily.com) Original source Spin-orbit torque (SOT), an important phenomenon for developing ultrafast and low-power spintronic devices, can be enhanced through Berry phase monopole engineering at high temperatures. In a new study, the temperature dependence of the intrinsic spin Hall effect of TaSi2 was investigated. The results suggest that Berry phase monopole engineering is an effective strategy for achieving high-temperature SOT spintronic devices.
Published Asbestos: The size and shape of inhaled nanofibers could be exclusively responsible for the development of pulmonary fibrosis
(via sciencedaily.com) Original source The pathogenic potential of inhaling the inert fibrous nanomaterials used in thermal insulation (such as asbestos or fiberglass) is actually connected not to their chemical composition, but instead to their geometrical characteristics and size. This was revealed by a study conducted on glass nanofibers.
Published Engineers invent octopus-inspired technology that can deceive and signal
(via sciencedaily.com) Original source With a split-second muscle contraction, the greater blue-ringed octopus can change the size and color of the namesake patterns on its skin for purposes of deception, camouflage and signaling. Researchers have drawn inspiration from this natural wonder to develop a technological platform with similar capabilities for use in a variety of fields, including the military, medicine, robotics and sustainable energy.
Published High-performance stretchable solar cells
(via sciencedaily.com) Original source Engineers have succeeded in implementing a stretchable organic solar cell by applying a newly developed polymer material that demonstrated the world's highest photovoltaic conversion efficiency (19%) while functioning even when stretched for more than 40% of its original state. This new conductive polymer has high photovoltaic properties that can be stretched like rubber. The newly developed polymer is expected to play a role as a power source for next-generation wearable electronic devices.