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Categories: Chemistry: Inorganic Chemistry, Geoscience: Geography
Published Taking photoclick chemistry to the next level
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Researchers have been able to substantially improve photoclick chemistry. They were able to boost the reactivity of the photoclick compound in the popular PQ-ERA reaction through strategic molecular substitution. They now report a superb photoreaction quantum yield, high reaction rates and notable oxygen tolerance.
Published Using evidence from last Ice Age, scientists predict effects of rising seas on coastal habitats
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The rapid sea level rise and resulting retreat of coastal habitat seen at the end of the last Ice Age could repeat itself if global average temperatures rise beyond certain levels, according to an analysis by an international team of scientists.
Published Unveiling global warming's impact on daily precipitation with deep learning
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A research team has conclusively demonstrated that global warming stands as primary driver behind the recent increase in heavy rainfall and heatwaves using deep learning convolutional neural network.
Published Surpassing the human eye: Machine learning image analysis rapidly determines chemical mixture composition
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Machine learning model provides quick method for determining the composition of solid chemical mixtures using only photographs of the sample.
Published Rare 14-ft smalltooth sand tiger shark washes up on Irish coast
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Scientists believe a huge 14ft smalltooth sand tiger shark, which washed up at Kilmore Quay, Co. Wexford, earlier this year, represents the first of its species to have been found in Ireland's waters. Two other individuals of the same species also washed up on the UK coastline, suggesting this species' geographic range has shifted. The scientists believe these rare finds may offer a window into the future, with more and more species traditionally confined to more tropical waters expected to visit Irish and British waters.
Published New 'droplet battery' could pave the way for miniature bio-integrated devices
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Researchers have developed a miniature battery that could be used to power tiny devices integrated into human tissues. The design uses an ionic gradient across a chain of droplets -- inspired by how electric eels generate electricity. The device was able to regulate the biological activity of human neurons. This could open the way to the development of tiny bio-integrated devices, with a range of applications in biology and medicine.
Published A first for ferrocene: Organometallic capsule with unusual charge-transfer interactions
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An organometallic capsule that can reversibly assemble and disassemble in response to chemical stimuli was recently developed by chemists. Comprising ferrocene-based bent amphiphiles, this new capsule can act as a host for various types of guest molecules, such as electron acceptors and dyes. Thanks to the controllable release of its cargo, the capsule would find applications in catalysis, medicine, and biotechnology.
Published Direct power generation from methylcyclohexane using solid oxide fuel cells
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Methylcyclohexane is very promising as a hydrogen carrier that can safely and efficiently transport and store hydrogen. However, the dehydrogenation process using catalysts has issues due to its durability and large energy loss. Recently, researchers have succeeded in using solid oxide fuel cells to generate electricity directly from methylcyclohexane and recover toluene for reuse. This research is expected to not only reduce energy requirements but also explore new chemical synthesis by fuel cells.
Published Enhanced chemical weathering: A solution to the climate crisis?
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Could blending of crushed rock with arable soil lower global temperatures? Researchers study global warming events from 40 and 56 million years ago to find answers.
Published Historic red tide event of 2020 fueled by plankton super swimmers
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A major red tide event occurred in waters off Southern California in the spring of 2020, resulting in dazzling displays of bioluminescence along the coast. Now, for the first time, a study has pinpointed how the plankton species Lingulodinium polyedra -- a dinoflagellate -- was able to create such an exceptionally dense bloom. The answer lies in dinoflagellates' remarkable ability to swim, which lends them a competitive advantage over other species of phytoplankton.
Published Quantum computer unveils atomic dynamics of light-sensitive molecules
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Researchers have implemented a quantum-based method to observe a quantum effect in the way light-absorbing molecules interact with incoming photons. Known as a conical intersection, the effect puts limitations on the paths molecules can take to change between different configurations. The observation method makes use of a quantum simulator, developed from research in quantum computing, and offers an example of how advances in quantum computing are being used to investigate fundamental science.
Published Past abrupt changes in North Atlantic Overturning have impacted the climate system across the globe
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Abrupt climate changes have affected rainfall patterns worldwide in the past, especially in the tropical monsoon region, a new study shows. An international team of scientists used dripstones from globally distributed caves together with model simulations to analyze the global impacts of rapid Northern-Hemisphere temperature increases, the widely studied Dansgaard-Oeschger events, that repeatedly occurred during the last ice age. The comparison of stalagmite and model data shows in unprecedented detail how these abrupt changes and the associated modifications of the Atlantic overturning circulation, AMOC for short, have affected global atmospheric circulation.
Published Making the invisible, visible: New method makes mid-infrared light detectable at room temperature
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Scientists have developed a new method for detecting mid-infrared (MIR) light at room temperature using quantum systems.
Published Scientists use quantum device to slow down simulated chemical reaction 100 billion times
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Using a trapped-ion quantum computer, the research team witnessed the interference pattern of a single atom caused by a 'conical intersection'. Conical intersections are known throughout chemistry and are vital to rapid photo-chemical processes such as light harvesting in human vision or photosynthesis.
Published Breakthrough in beta-lactam synthesis using nickel catalysts
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Researchers have made a significant breakthrough in the field of asymmetric synthesis of beta-lactams, which are prominent in bioactive compounds. Their innovative approach employs nickel and hydrocarbon sources that are abundant on Earth to access value-added beta-lactam products. The employment of nickel-hydride catalysis and alkenyl dioxazolone derivatives gives rise to the selective formation of four-membered lactam products.
Published Light regulates structural conversion of chiral molecules
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A team of chemists have developed a novel concept in which a mixture of molecules that behave like mirror images is converted to a single form. To this end, they use light as external energy source. The conversion is relevant e.g. for the preparation of drugs.
Published Hot chemistry quickly transforms aromatic molecules into harmful aerosols
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A research group has established key early steps in the conversion of aromatic molecules, a major constituent of traffic and other urban volatile emissions, into aerosol. Their findings increase understanding of the chemical processes that degrade urban air quality and influence climate change.
Published Scientists develop fermionic quantum processor
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Researchers have designed a new type of quantum computer that uses fermionic atoms to simulate complex physical systems. The processor uses programmable neutral atom arrays and is capable of simulating fermionic models in a hardware-efficient manner using fermionic gates. The team demonstrated how the new quantum processor can efficiently simulate fermionic models from quantum chemistry and particle physics.
Published Steam condenser coating could save 460M tons of CO2 annually
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If coal and natural gas power generation were 2% more efficient, then, every year, there could be 460 million fewer tons of carbon dioxide released and 2 trillion fewer gallons of water used. A recent innovation to the steam cycle used in fossil fuel power generation could achieve this.
Published The trio -- nickel, palladium, and platinum -- for enhanced hydrogen evolution
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A research team enhanced hydrogen evolution catalyst through stepwise deposition.